It would help greatly if you could provde infomation that'd make it alot easier to pin-point the problem.
Different guys see things in different ways, so certain info will be of more benefit than others - so go info "overload and then I'm sure you will find the answer to your query, and posible some new "ideas" for you to try out / consider for future setups.
If you could provide:
Full suspension / LSD / aero / brake settings
What tyres being used?
Power / weight
Confirm this happens ONLINE - if so, free run or race??
What track(s) this happening on?
The guys that have commented so far know what they're talking about, but to be 100% sure, seeing the above info will help to either confirm or "rule out" possible fixes. It also means others can dial in this (setup) to their car and try it and see for themselves what's happening - which is very helpful.
Taking into account what's been said above, and also not knowing much details about the car. For a FR car to have it's outside front wheel "lighting up", after brake but before throttle - to means this scream in-balance in how the weight of the car is being handled by the setup.
I reckon it should be pretty easily fixed, but without knowing your setup it's almost impossible to give accurate feedback.
The tyre going red means it's under "stress" - but this can be caused by a number of factors.
The solutions offered already are good solutions, but problem still happpens. In a way this is good, it highlights that basic driving "errors" don't seem to be the cause, so we can go straight to the setup (if you could provide it please?).
Your posts don't indicate that you're running "crazy" settings for camber and toe, so I'm presuming this will be down to the springs, roll bars and dampers.
These are weird - sometimes you can look at these and think "hey, yeah - spot on", then drive the car and it's ****ed, likewise, you can set them to levels where you 'think' it'll never work, but it does.
It's probably a mis match of spring, roll bar and damper settings, the C63 has a pretty good weight distribution so there shouldn't be anything running near max or minimum, but sometimes as little as a roll bar being one click "out" can make a huge impact on a setup - possibly the difference between a car being drivable or not.
If you want something "balanced" to start off with, maybe try:
Springs
Fr - 9.5
Rr - 8.5
Dampers
Fr - 5 & 4
Rr - 4 & 4
Roll bars
Fr - 3
Rr - 4
That's kinda a medium strength starting point. If you want something stiffer, try:
Springs:
Fr - 10.8
Rr - 9.6
Dampers:
Fr- 7 & 7
Rr - 6 & 6
Roll bars:
Fr - 2
Rr - 3
Your LSD settings don't seem bad and the camber setting suggested are well within the norm. For a Fr car I'd run some where around 2.2-2.8 front and 1.5-18 rear as a starter.
Without knowing what tyres and power the car is at, toe is a little harder to guess, but negative front and positive rear is at least the right "direction", normally something around -0.10 fr and +0.05-0.15 rear is an "ok" start. But this is heavily dependent on the power of the car and tyres being used.
As Motor city said, ride hieght is a personal thing, for powerful FR and MR car, i'd be tempted to leave it near stock height, rather than "slamming" the car. If high power and lower grip tyres being used, maybe run the rear stock and front end down 3 / 6 /9mm lower. Again, heavily dependent on power and weight.
Let us know the details of your setup and I'm sure someone will "nail it" and sort you out
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